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1、专业.专注.学习参考 .有机化学 II 总复习（一）完成反应式解答 H+2C2H5CHCOOHOHOOOOC2H5C2H5 HOOCCH=CHCHCOOHCOOHOOO COOHHOOCOHOOCO COOHCOOHO C6H5COONa +CH2CHCH2BrC6H5COOCH2CH=CH2+CO2NaCH2BrBrCH2OCBrO+CH3CH2CH2COOHBr2POH-H2OCH3CH2CHCOOHBrCH3CH2CHCOOHOH COOHClHHPb(OAc)4,I2CCl4RONaClHHI OOOC2H5OHH+C2H5OHOOOC2H5OHOC2H5OOOC2H5 COClO2N
2、HNNaOHH2O+NCOO2N+CH3NH2CH3OOCH3ONHCH3OH C2H5OHOCH3CH3OC2H5ONaCH3CH3OOHOC2H5 NOHLiAlH4H2ONH 专业.专注.学习参考 .H3O+LiAlH4(1)(2)OOCH2OHCH2OH H2,Pd/BaSO4硫喹啉ClCOClCHOCl C2H5OHH+CH3CH=CHCH2CH2COC2H5ONaCH3CH=CHCH2CH2CH2OH H+(CH2)12COOCH3COOCH3Na二 甲 苯(CH2)10OOH COOC2H5COCl(CH3CH2)2CdCOOC2H5COCH2CH3 CH3CH2COCl(CH3
3、)2CuLietherCH3CH2COCH3+OOC2H5MgBrH+/H2O乙醚HOCH2CH2CH2CH2CC2H5OHC2H5 H+/H2OCNC6H5MgBrCO NaOC2H5CH2COCH2CH3COOC2H5OOCH3+COOC2H5OCH3COOC2H5C2H5ONaCOCH2COOC2H5O H+COOC2H5COOC2H5C2H5ONaOH-2H2OOOH5C2OOC OOCOOC2H5+CH3CH2NO2CH2=CHCOCH3NaOCH3CH3CHCH2CH2CCH3NO2O+OCOOC2H5COOC2H5C6H6NaHOCOCOOC2H5+CH2CN(C2H5O)2CO
4、C2H5ONa甲 苯CHCOOC2H5CN 专业.专注.学习参考 .+H+NaHCH3OHCOOC2H5etherCH3OCHO CH3CH2CH2COOC2H5LDA,THFCH3CH2ICH3CH2CHCOOC2H5Li+CH3CH2CHCOOC2H5CH2CH3 C2H5ONaNCCH2COOC2H5CH3COCH=CHPhNCCHCOOC2H5CHCH2COCH3 CH3COCH3(1)(2)CHOOH+ClCH2CO2C2H5NaOC2H5OH/H2OH+/CH3OCH3OCOOC2H5CH3CHO OClCH2COOC2H5KOC(CH3)3t BuOH+OCOOC2H5+CHOB
5、rCH2COOC2H5Zn/C6H6H+1.2.OH-/H2OH+/1.2.CH=CHCOOH C2H5OC(CH2)4COC2H5OONaOC2H5(1)(2)NaOC2H5BrC2H5(1)(2)OH-/H2OH+CO2C2H5OCO2C2H5OC2H5OC2H5+H3O+NHO对 甲 苯 磺 酸甲 苯ClCH2CH=CH2(1)(2)NOCH2CH=CH2 NHOOKOH(s)PhCH2BrH2OOH-N-K+OONOOCH2CH2NH2 H3CHNH2PhCCOBr2/OHH3CHPhCNH2 NHOOBr2/OHNH2COO-BrNO2Zn/OHH+NHNHBrBrBrBrH2NNH
6、2 专业.专注.学习参考 .C6H5CONH2P2O5C6H5CN CH3OHNaN3CH2CClOCH2N=C=OCH2NHCOOCH3 CO2HSOCl2CH2N2Ag2OH2OCC HN2OCH2COOH H2O(1)(2)CH2NHCOCH3O2NH2/PtLiAlH4CH2NHCOCH3H2NCH2NHCH2CH3H2N H2/PtOCH3CH2NH2+压力，NHCH2CH3 NHCH3HHOHCHO/H+NCH3Omannich reaction OHCH2NH2HNO2O HClNH2OHNaNO2O。CH3COOCHCH2CH(CH3)2C(CH3)3500 CC=CH(CH3
7、)3CHCH(CH3)2。500 CCH3BrHDCH3CH2HCCCH3COOCH3DOCCH3OHCH3CH2HCCC=CCH3CH2CH3HD CH3CH2CH2CHN(CH3)3OH CH3CH3CH2CH2CH=CH2 N(CH3)3OHCH3CH3+CH3CH3。N(CH3)2CH2CH3CH3H2O2200 CN(CH3)2CH2CH3O-CH3+CH2CH3CH3 专业.专注.学习参考 .NHCH3CH3IAg2OH2O过量NCH3CH3CH3+OH-NCH3CH3CH3+NClNCH3ClHONaOHH2OClHON=NCH3 CH3C2H5CH3OCH3CH3OCH3CH3
8、C2H5 CO2CH3CO2CH3.HCO2CH3CH3O2C()()HHCO2CH3CO2CH3 CH3C2H5+C2H5CH3CH3+CH2N2CH3OCOCCCOOCH3+NNCOOCH3COOCH3+ONCH2=CHCOOCH3NOCH3OOC HOOC2H5HOOC2H5OC2H5O CH=CH2CH2 +OCH3CH3CCCH3OOCCOOCH3CH3OCOOCH3COOCH3CH3 专业.专注.学习参考 .+SHCHOHCl/ZnCl2SCH2Cl+COOHSBr2CH3CO2H25 CoCOOHSBr SH2SO425 C。SSO3H+NNCH3IHNNHCH3I-+(1)(2
9、)NCH3CH3NaNH2PhCOClNCH2COphCH3 NH2SO4HNO3NNO2NNO2+H3O+CH3NC6H5Li OCHONCH=CHONCH2CHOOLi ClClNCH3ONaCH3OH,ClNOCH3 NCH3RLiCH2=CHCNNCH2LiNCH2CH2CH2CN C2H5ONaNH2NNaNO2,HClCuBrCH2(COOC2H5)2H3+OBrNCH2COOHN OCHONCCH2COOC2H5CH3COONH4OCH=CCNCOOC2H5+NCH3CCH3ONaNH2NCH=CCH3 专业.专注.学习参考 .+HHOHOHCH2OHCH2OHOPhNHNH23HAcHHOHOHCH=NNHphCH2OHNNHph OCH3OCH2OCH3OCH3CH3OCH3OOCH2OCH3OCH3CH3OOH3O+OHCH2OCH3OCH3CH3OOOHCH2OCH3OCH3CH3OCH3OOHO+HHOHOHCH2OHCH2OHOAg(NH3)2+COO-HHOHOHCH2OHHHOOHHCOO-HHOHOHCH2OH CHOHOOHOHCH2OHHHHHHOOOOCHOCH2OHHHHOHOHOHOHOHCH2OHONaBH4CH3COCH3HCl
有机化学(下)复习题_完成反应式答案
