试题库三——完成反应式题及解答

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1、试题库三完成反应式题及解答1(CH 3)2C=CHCH 3HBr2CH3OCH=CH 2+ HBr3CH3CH2CH=CH2 CH3CH2CH2CH2OH4CHCH=CH B2H632 H2O25(CH3) 2 C=CHCH2CH3 O 3 Zn 粉 ,H 2O22ClCH CHCH OH6CH=CHCHOH22OH7CH3CH2CH2CCH + HCl （过量）8CH3CH2C CH + HBr （过量）9CHCHC CCH + KMnO4H +32310CH3CH2CCCH3 + H2OH2 SO4HgSO 411CH2=CHCH= CH2+ CH 2=CHCHOCH312+ HBr131

2、4151617181920高温+ Cl 2+ Cl2CH 2CH 3+ Br2CH(CH 3)2高温+ Cl 2CH 3 O3H2OCH3 O3CH=CH 2H2O KMnO 4CH=CH 2CH 3 H2SO4 H2O 21+AlCl 3CH2Cl 2CH 32223+ HNO3SO3HBr 2FeCH324SO3 /H2SO425+ KMnO 4H+26CH=CH2 + Cl 2MgCO 2H+27 C 6H 5CH 2ClH 2 O28 CH 2=CHCH 2Br+NaOC 2H 529CH=CHBrCH 2 BrAgNO 3乙醇+室温30+Br 2KOH- 乙醇CH 2=CHCHOCH

3、 2 Cl313233NaOHH2O, ClOH -+ H2OSN 2历程CH 3 ClCH 3OH-+ H 2OSN1历程ClCH334EtONaBr35BrKOH-乙醇36CH2=CHCH2ClCH2=CHCH2CN37 (CH 3) 3CCl + NaOHH2 O38 (CH 3) 2 CHCH2CH2OH + HBr39OH+ HCl无水 ZnCl 24041AlCl 3OHOCH 3CH 2CH 2OCH 3+ HI（过量）+ HI（过量）42 O CH343(CH3) 2CHBr + NaOC2H544KMnO4CH 3 CH 2 CH 2CH 2CHCH 3 OH -OH4546

4、47CH 3+ Br2OHCHCHHIO43COOH+ CH3CH2CHOHIO 4COCHCHCHCHO322248 CH 3CH 2 CH 2 CHCH 2CH 3浓 H2SO 4OH（分子内脱水）49CH3COCH2CH3 + H 2N-OH50 Cl 3CCHO + H2O 51 H 3CCHO+KMnO 452CH3CH2CHO稀 NaOH53C6H5COCH3+ C 6 H5MgBr H2OH +54O+HNNHC H52655O+H2NOH56(CH3) 3CCHO浓 NaOH57O +(CH 3)2C(CH无水 HCl2OH) 2O +Na 2CrO 7H +5859CHOKM

5、nO 4室温60OCl2,H 2OCCH 3-OHOH +61CCH 3+Cl 262CH2=CHCH2CH2COCH3 + HCl63CH CHO + CH COCH6533 稀 OH-,64CH 3COCHCO 2C2H5 H,+ H2OCH 36566CH 3COCHCO 2 CH 3浓 NaOHCH 2CO 2CH3CH 3CH 2 CHCOOHOHCO 2CH 3稀 H+67COCH 368CH 3HO 2 CCH 2COCCOOHCH 369 CH 3CH 2CHCOOH NaOH-H 2 OCl70CH 3CHCH 2COOHOHO71O NaOH-H2OH 3CCH 3稀 H2

6、SO472CH 3CH 2CCOOHOH73CH3CH2COCO 2H 稀 H2SO47475CH 3CHCOCO 2HCH 3COOHCOOHCOOH76 NaOH,O O H+,77CH 3CH 2COOH +PCl 278Na 2Cr 2O 7 -H2 O79(CH 3) 2CHOH+ H3CCOCl80HOCH2CH2COOHLiAlH 481NCCHCHCN + HONaOH+H22282CH 2COOHCH 2COOHBa(OH) 2CH 383CH3COCl +无水AlCl 384 (CH 3CO) 2 O +OH85CH3CH2COOC2H5NaOEt86CH3COOC2H5

7、+ CH 3CH2CH2OH 87CH3CH(COOH)288COOH +HCl89 2COOH+ HOCH 2CH2OH90LiAlH4COOH9192HCOOH +OHCH 2CH 2COOC 2H 5NaOEtCH 2CH 2COOC 2H 5CONH 2-93OHNN + CH CHBrCH 94(C H)3253395 (CH 3) 3NCH2CH2CH2CH3 +Cl -+ NaOH96CH3CH2COCl +H3CNHCH 3N(C 2 H5 )2979899+ HNO 2CH 2CH 2COOC 2H5NaOC2H 5CHCH Br32CH 2CH 2 COOC 2H 5？ N

8、aOH / H2O？H+ /H2OCH 2CH 2CH 2CNH +/ H2OH+OH？100H2O2？CH3SCH330%HAc101浓碱H3COCHO？102103104KMnO 4 / H +N？CH 3CH 2CHOOH -NaBH 4OH2OHCNH +105CHO+ HS(CH2) SHHCl3106 CH3CH2OH NaBr / H 2SO4? CH3CHO? Na2Cr2O7? Mg / 乙醚 H2O HOCH 2CH2OH107C6H5CHO+ CH 3CH 2CH 2CHOOH -108H2S+O1:1O109 H 2/Pd?KMnO 4 Al 2O 3 OH -110

9、CH 3CH 2CH 2CHO +H 2N111 (CH 3)2CHCH2COOHP + Br 2112C OH2OOH +COHNO 3113OCH 3H2SO4114H2 /PtN115O +HCN116+CH 2CH 2 N Me 2CH 2CH 3117CH 3CH 2CH 2CHO + NaHSO 3118OC +H2OBr119ONaOH + Cl 2CH 2CNH 2CH3120HNO 3OH2SO4121CH 3CHO + CH3CH 2OH无水 HCl122+-(CH 3CH2)3NCH 2CH 2COCH 3OH123COOH- CO2NCOOH124BrCHOZn-HgH

10、Cl 125COOHCOOHCH 3 COCH 3?Na2CO 3?126(CH3CH2CO)2O +NH2127ONaOHCH 3(CH 2)4CCl 2Cl128H2NNHCONH 2C6H5COCH3129+ClCH2CH2NMe2OH-CH2CH3130COOH SOCl 2CH3NAlCl 3131CHCOOHCHCOOHCH 3132HNO 3NH2SO4HCl133COClNH 3Br2NaOHCHO1343 C6H 5HNNH 2CH 2OH135Mg? CO2SOCl2C6H5CH2Cl 干醚? H2O136H3CNHCOCH3 +HNO3HOAc137(CH 3)2CHCH

11、CH 3OH-+N(CH 3)3138HNO 3SCOCH 3 H2SO4139COOHCOOH140NH3?Na OH +Cl2?CH 3(CH 2)4 COCl141CH 2ClHCN?H 2O?NaCNC OCH 2Cl?H2O?142NH 2 + CH 3SO2Cl?NaOH?143144COOHHNO 3H2SO4 ?CH2CH3HNO3?CF3HNO 3145?H 2SO4 OH146147+ (CH 3CO)2ONH 2OHCH2COOH148CH 2COOH?Zn-Hg?CH 2COOHAlCl 3HClSOCl2?AlCl 3?149NHNaNO 2+ HClOH25?OH-

12、?HOCHO+150Ag(NH 3)2OH-151COOHPCl5+152 phCH CH-NMe22CH 3O-153CH 2SH+ HgOCHSHCH 2SH154NKMnO 4H+CHO +OHOAc155H2NNHCNH2156CHO稀OH-+ CH 3CHO157OCH MgIH 2SO4 B2H6CrO3?3? H3O+ H2O2158HNO 3CH3CH2CH2CH2SHOHOAc159 3 2 3+2NNHNH2CH CH CCHONO 2160HOCH2CH2CHOHCN?H3O+?CH 3161KMnO 4?P2O5?H+CH 3CH3162CH3?Fe(CH3CO) 2O

13、?HNO 3?H3O+?HCl?H 2SO4NO2163CH 3CH-CHCHKOH？O 3？H2 O？+？3乙醇ZnCH 3Cl164 CH 2 =CH-CH=CH 2+ CF 3-CF=CF 2180165CH2=CH-CH=CH 2 +CH=CHCN166CH3CH2 =CH-CH=CH 2 +CH=CHCHO167+ ？+？ZnCl 2CH 2Cl60168HCHO ，HCl?Cl 2?Na OH?Zn Cl 2FeH 2O169 CH 3CH 2 CH-CCH+H2OHgSO 4H2SO 4CH3CH CH OCHCH3+HI (过量 )？+ ？170 3 2CH3CH 317117

14、2CHCH 3稀 HNO 3回流CH 3CH 2OHMgCH 3C CH+ PBr 3？乙醚？ +173174HOCH 2NBSCCl 4+HBrCH 3175 CH 3CH-CH-C-CH 32HIO 4OH OH OHCHCCHCHCHCHNa?CH 3I液氨1762223177 CH 3CCHNa?CH 3CH 2Br?H 2液氨液氨Pd / BaSO4NaCH 3C CCH 3+ H2?液氨?Na?液氨178179180181182183184185186187188189190191192193H2 CCHCH 2CH 3H 2 OHIO 4?OBrNaOHEtOH+COCl无水 A

15、lCl 3CH=CHBrKCNCH2 ClCH=CHBrNaOC2H5ClOCH 2CH 3HIOCH3 +HIO+OO+ O OO+ O OO+ OOCH 3HI+ ClFeCl 32+ HNi280HBrCH 3CH 3CH3194HBrCH3195O3Zn /H2O196CH 2H+ H O2197CH2B2H6 H2O2 /OH -198 CH 3CH=CHCH 2CH 2CH 2OH + KMnO 4 199BrONa+CH 2BrBr200Mg?干醚Cl201BrMg?干醚Cl?H2 OH+?202203BrMgCH 3COOH?干醚CH2 Br+HIO4?OH OHCH(CH 3

16、 )2204+CH2=CHCH 3?H2 O/H+?8090O 2?110120 0.4MPaCH(CH 3 )2205AlCl 3+?206+ Br 2H2OH 3 CCH 3207 CH CCH 2 CH=CH 2+ Br 2 (1mol)208H3CCH(CH 3)2KMnO 4H +CH 3?209+ HNO3H2SO 4?+?211H2H2 / Ni?C80211212CH=CH 2 + Br 2CCl 4?CH 2HBr？Mg？D2 O乙醚？DBrMg？过氧化物乙醚213Cl2？KOH乙醇214+ CH 2 =CH-COOEt215+Br 2216 (CH 3)2C=CH 2+HC

17、l217(CH 3)2C=CH 2+ HCl过氧化物218CH 2CH 2CH3NBS？Me3 COK219KMnO 4220PhCH 2CH2CH3光?KOHCl2醇冷 稀 KMnO 4?KMnO 4?H+221CH(BH3)2?H2O2?3OH-CH 3222+CH 3CH=CH 2无水 AlCl 3OCH 3223CHMe 2+ CH2=CMe 2无水 AlCl 3224CH 3HI?+?OC2H5225 CH 3CH2CCHHOBr?CHCH=CH2+ HOCl2263？KMnO 4？?227CH2=CHCN+228浓 H 2SO4?浓 H2 SO4?060229 CH3CH2CCCH

18、 2CH3+ H2Na?液氨230 CH3CH2CH=CH 2 + Cl 2500 231 O3 Zn ，H2OCH3232+ NBS233NBS234 CH CH+ HCNCu2Cl2235 CH3CH2CH2CH3 +Br2 127 236?OH -H 2OCH3CHCH3OHH 2OCH CH CH Br+ ?醇?CH CHCOOH23732232238 CH 3CHO+?乙醚?H2OCH 3CH-CHCH 3OH CH3Cl239 O2NNO2+H 2ONaHCO 3NO 2ClH 2O240NO 2+Na2CO3Cl241BrMg?Br干醚OHH2SO4242 CH 3CH-C-CH

19、 2CH 3CH 3CH3243CH3H2OOH +Br2244 CH 3Cl 2 NaCNCl 2?Fe光? HO+3? B2H6-? H2O2/OH?245CH 2CH2 CH2 CHCH3AlCl 3Cl246NO2HNO 3H SO2 4247CH3+HBrCH 3-C-CH 2OHCH 3CH3H +248 CH CH -C-CH332OH试题库三：完成反应式答案1. (CH3)2C-CH 2CH 3 Br3.B2H6 H2O2HBrH O或2OH-OH-H2O25(CH3) 2 C=O + CH3CH2CHO7CH3CH2CH2CCl2 CH39CH3CH2COOH + CH3CO

20、OH2CH3OCHCH3Br4CH3CH2CH2OH6 Cl 2+H2O8 CH3CH2CH2CBr2CH310. CH 3 CH 2CCH 2CH 3+CH 3CH 2CH 2 CCH 3OO11.CHOCH312. BrCl13.CH 2CH 3CH 2CH 3Br15.+Br17. CH3-C-CH2CH2CH2CH2CHO O19COOHH2CCH 2 Cl21.或Br23.SO3HClCl14.C(CH 3)216.Cl18. CH3CHOCH 320. OHCH 322.NO 2CH 324SO3H25. HOOCO27. C6H5CH 2MgClC6H5CH2COMgClCH=C

21、HBrCH 2ONO 229.CH 2OH31.CH Cl3CH333.+HOOH35.37(CH3) 3C-OH39. Cl41.ICH 2CH2I43(CH3) 2CH- O-C2H545. CH 3CH 2CH-CCH 3 OH OCH 347.BrBrOHNOH49.CH 2CCH 2CH350Cl 3CCH(OH)2OMgBrOH53.C6H5-C-C 6H5CH -C-C H5656CH 3CH 355.N-OH(CH3) 3 CCH2OHH 2CCH 3O57.OCCH 3CH226. CH-CH 2 Cl ClC6H5CH 2COOH28. CH 2=CHCH 2OC 2 H5

22、BrCHO30. BrOH32.CH 334CH 3NaCN36乙醇,38(CH3) 2CHCH2CH2Br4042. CH 2CH2CH 2CH2CHCH3II44. CH3CH2CH2CH2CCH3CH3O46.OHOH48CH3CH2CH=CHCH2CH351. HOOCCOOH52. CH 3CH 2 -CH-CHCHO OH CH354.NNHC 6H 556 (CH3) 3CCOOH +58HOOCCH2CH2CH2COOH59.COOHO61. CCH 2 Cl63C6H5CH(OH)CH2COCH3OH2CC65.OH2CCO67. COCH 369. CH3CH 2CHCOO

23、NaOHCH 371. CH 2CHCH 2COONaOH73.CH 3CH 2CHO+ CO 2OC75.OC O77. CH3CHCOOH Cl79.H3CCOOCHMe 281NaOOCCH2CH2COONa HOOCCH2CH2COOH82.O84. OCOCH 360. COO - + CHCl362 CH3CH(Cl)CH2CH2COCH364. CH3COCHCOOH CH3OC66.H 3CH 2CHCOOCHCH 2 CH 3CO68.CH3CH 3COCHCH 370. CH 3CH=CHCOOHCH 372. CH 3CH2 C=O + HCOOH74. CH 3CHCH

24、O + CO 2CH 3CH 2 CH 2COONa76.OHCOOH78.COOH80HOCH2CH2CH2OHCH 383.COCH 3O85. CH 3 CH 2CCHCOOEt CH 386CH3COOCH2CH2CH3 + CH 3CH2OH87 CH3CH2COOH + CO28890ClCOOHCH2OH8991COOCH 2CH 2OOCOOCH92O93COO -COOEtN+ NH3+-95 (CH+-94(C H ) NCHMe Br) NCHCHCHCH +Na+ Cl+OH2532332223N(C 2H5)296H 3CNCCH 2CH973CH3ONOCOOC H

25、COOC2H5-C2H5OOCCH2CH3 HOOCCH CH3CH2CH3O2 5OO2ONa +O98.CH2CH2100. CH 3SCH399. CH 2CH 2CH 2COOHOOHCH 2COOCOOH101.H 3COCOONaH 3COCH2OH103 CH 3CH 2CH=CCHOCH3CH2CH=CCH2OHOHCH3 OHCH 3104CNCOOH106. CH3CH2MgBr CH3CH2CHCH3 CH3CH2CHCH 3OHOOCH2-CH2108. HSCH 2CH2OH110. CH 3CH 2CH2CH NCOOH112.COOH114NH116. CH=CH

26、 2118.COOH102.NCOOHS105.S107. C6H5CH=C-CHO CH 2CH 3109OHOCH 3OHCOCH 3111. (CH 3)2CHCHCOOH Br113O2NOCH3OH115.CNOH117. CH3CH2CH2CHCH3CH2CH2CHOSO 3Na119. CH 2NH2120.CH 3ONO 2OCH3121. CH3CHOCH3COOH122. CH2=CHCOCH3124.BrCH3126.NHCOCH2CH3128. C6H5C=NNHCONH 2 CH3OCOClC130.NNCH3123.N125. COOH127CH 3(CH 2)4N

27、H 2129 ClCH=CH 2OCHC131.OCHCOCH 3ClCl132.NO 2133.CONH2NH2NHCHNNHph134NNHph135C H CH MgCl C6H5CH2COOH C6H5CH2COCl652CH 2OH136 H3CNHCOCH 3137 (CH 3)2CHC=CH 2138NO2139COCH 3OO2NS140 CH3(CH 2)4CONH 2CH 3(CH 2)4NH 2CH 2 ClCH 2ClCH2CNCH 2COOH141.HOC CNHOC COOHHOCCOOHHOC COOHCH 2 ClCH 2ClCH2CNCH 2COOHCOOH1

28、42.CHSOHCHSON-+143.32N3Na2NO 2COOHCF3144.145.NO2OCOCH3147.CHCOOH146.NH2CH2COCCH2CH2COOHCH CH CH COOHCH CH CH COClO148.CH2CO222222OO+-HOCOOH149.N 2 ClN=N150.OH151.COCl152.phCH2CH=CH2CH 2SHgCOOH153.CHS154.CH 2SHNO156.CHCH 2CHO155.CHNNHCNH 2OHOHCH 3CH 3CH 3158.CH3CH2CH2CH2SO 3H157.CH 3OHO159.O2NNHN=CCH2CH3160.OHCH3HOCH 2CH 2CHCNNO2OHOOOOCH 3CH3CH 3CH3COOHCHNO 3CO162.COOH