配合物稳定常数资料

《配合物稳定常数资料》由会员分享，可在线阅读，更多相关《配合物稳定常数资料（13页珍藏版）》请在装配图网上搜索。

1、配合物稳定常数资料配合物稳定常数Stability Constants of Coordination Compounds络合反应的平衡常数用配合物稳定常数表示，又称配合物形成常 数。此常数值越大，说明形成的配合物越稳定。其倒数用来表示配合 物的解离程度，称为配合物的不稳定常数。以下表格中，表（1）中除 特别说明外是在25C下，离子强度I =0；表（2 ）中离子强度都是在 有限的范围内，1”0。表中闻表示累积稳定常数。金属-无机配位体配合物的稳定常数Stability Constants of Metal Ion-Inorganic Coordination Compounds序号配位悻 iL

2、hgiWd)瓮憎蔼于 (Mttfil Lem睥体曲“ fNiibibt-rof 叩皿lH)1N田UJ.2M,7AI5AuJ+410JCdi+心声i.iS.-LTS.b. 19.7. JIdCo2Cu*M3,1此勤LuiT心AS43L7 刑LU2.133MZ .腌】2LJj.2咬福8.&.17.5.18J!J.28萨1,1牌嬴2.80,5.04,6.77,7,8.71 .t.74rd2*ll.(i,lN.512fiLll75Z.S时，635JZn14l2Bi*1心1.3*1，整局 00,A7A2J7.113,fi.20.S.di+嗥*1141u+25,9Cu1虬网1珈In341,21.30,1.

3、88Pb1.2341.77,2.603.00,230Pd21,2,3 A5.17342.12.70.14.90Rh5*2,3,心.6143,163,17.6,18.4,17.2Sc3*1,22.0K3.(静1,231.11,11,1.46TP*1.2.3.45.69.7.16.6.21.223.9.2923L6u“10.18丫3+11323ClA#1,233.(14,5.04,5.30Bi1,2342.44,4.7,5.0.5.6CdK1.2341,95350.60,2.80Co3*1142Cu42,35.5,5.7c1,20.1,-0.6Fe2*11.17Fe3-29.8Ilf1,23.46

4、.74J3.22.14.07J5.07In341.2341,62.44,1.70,1.60Pb21,231.42,223,3.23Pd2+1,2346.l,10.7,13.l,15.7Pt242,3.411.5,14.5,16.0Sb1.23.42263.494.18,4.72Sn21,234IS 1224203,1.48TP1,25.48.1443.60.15.78,18.0(1Th4141.38,0.38Zn2-1.2340.43.0.61,0.53,0.20Zr&123.40A1.3J.5J.24CAg*2,3.421.1,21.7,20.6Au4238.3Cd1.23.45.48,10

5、.60,15.23,18.78C23424.(1.2859.30.30635.0642.0Hg”441.4Ni2*431.3Zn21.2345.3,11.70,16.702 L605FaP，1,23,4S66.11.11.12.15.00 18.00.19.40,19.80Be2,1,2,34.99，&80,11.60,13.10B之11.42Co2r1(1.4Cr3*1,2,34.36,8.70,11.20C1(1.9Fe2-10.8F1.2355.28,9.30,12.06.15.77G1,2,34.49,8.1X),10.501,2.345,69.046.5,23.1.28.8,34.0

6、,38.011.03Inu1.23.43.70,6.4(1.8.60,9.80Mg2*11.30Mn2+15.48Ni2410.50Pb1.21.44,2.54Sbu1.23.43.0,5.7.8.3.10.9Sn2+1,234.08,6.68,9.50Th4*1,2348.4445.08.19.80,23.20TiO2+1.2345.4,9.843.7,18.0ZnK10.78Zr%L23,4S,69.4,17.223.729.5.33.5,38.36rAg41,2,36.58,11.74,13.68Bi5414363.63,14.95.16.80,18.80Cd2r1.2342.103.4

7、3,4.49,5.41C28.85Fe，11.88H矽1,23412.87,23.82,27.6029.83Bb2t1.2342.(X)3.153.92.4.47Pd2*4245TT1,230.72,0.90,1.08TH1.234ll.4h20.8U7.6031.827OHAg*U2.03.99A】5*1,49.27.33.03孑1.23414.33,18.73.206021.20Be2*1,2,39.7,14.0,15.21,2,412.7,15.835.2cP11.3Cd21,2344J7&33,9.02.8.62Co5*14.6Ce4*1,213.28,26.46Co2-1.2344.

8、3,8.4.9.7.10.2c1,2,410.147.8,29.9Cu2r1.23.47.04X68.17.00,185Fe2-1.23.4S.56,977,9.67.8.58Fev1,2=11.8721.1729.67Hg2*1,2310.621.8,20.91.23410.020.2,29.6.38.9Mg2*12.58Mn2*1,33.9,82g1,234.97,8.55,1133Pa4*1.23.414.0427.84,40.7,51.4Pb21237.82.10.85J 4.58PdK1,213.心方Sb%2,3,424.336.7,38.3sL18.9s110.4Thr1,212.

9、86,2537Ti%112.71Ln21.2344.40J1.30.14.14J7.66Zr441,23414.328.3.41.9.5S38NOBa210.92Bi5*11 26Ca2*10.28Cd加10.40时11.0Hg210.35Pb11.18TF10 33TP10.929pW14.6Ca2+14.6cP15.6Co2*16.1Cu2*146.7,9.0Hg2*212.38Mg2*15.7Ni2f1,25.8.7.4Pb21,27.3,10.15z1,28.7,11.010SCNAg41.2344.6,7.57,9.08,10.08Bi3+1,23,43.6l.673(MU.l,4.

10、805.50.6.10Cd2*1,2341.39,1.98,2.58,16C1,21.87,2.98Cu“L212.1L5.18C1,21.903.00F.1,23,45,62.21,3.64S.(Ml.6.30,6.20,6. 10I*，1.2349.08,16.86.19.70,21.70w1,2,31.184.64,1.81Pb1230.78,0.99,1.00Sn2,1,2,31.17,1.77,1.74Th1.21.08.1.78Zn21.2341.33,1.91,2.00,1011Ab1,28.82.13.46Cd2t1,23.92,6.44CiT1,231UJ7J222J3.S4

11、12.10理队2,3.4294431.90,33.24Pb235.13,63512so/Ag+11.312.7Bi%1,2,34,51.8,3.41.4.08,4.34,4.61)Ft/41,24.IM,5.381,2134,2 囱T+1.78.1.88,2.36nF*12APbZ12.75Pru1,23.R4成Th*1,23.32,5.50Zr4* 1,233.79.6.64,7.77金属-有机配位体配合物的稳定常数（表中离子强度都是在有限的范围内，1”0。）Stability Constants of Metal Ion-Organic CoordinationCompounds2海 t血

12、乙二胺四乙酸 (EDTA) KHOOCCH.hNCH.L.(puegn)#292fi |%s4-Vz aM9 2 +L *4%H g z +G a*4 +ra*rt3 +C 0 yc dpAB+OSB a2+A%(Metal ion)剃IMn a o 5 f d配位体 数目 (Numberpo oe22 12 3 18 s1838 .56i .gs63 90oo 62 诲.95gM k 5.2314 838 .72 3 .oUJ16 .311611 .=2 ZQO* Im716 12喜T产1232TiO2*1173Tlu1225时117.50vo2+118.0Yu118.32Zn2+116.4

13、Zr*119.42乙酸（Acetic acid） CH3COOHAg120.73,0.64Ba”10.41Ca2*10.6cf1,2,31.52.3,2.4Ce*123,41.682.69,3.13,3.18C2*侦IS,1.9Cr*1,2,34.63,7.0&9.60cu%2（rc）122. 16,3.20lnuU3,43.5OS.95,7.9O,9.08Mn129.844.06Ni121.12,1.81Pb2.52,4.0,6.4,8.5Si?1,2,33.3,6.0,73Tl3*17346.17,11.28,15.10,18.3Zn2+11.53乙酰丙丽A1X（3OC）128.645.5

14、(Acetyl acetone) CHaCOCH.CHaCd2*1.23.84.6.66Co2+1,25.40.9.54Ci2+125.96.11.7Cu2+1.28.27,1634Fe2+125.07,8.67Fe3+12311.422.1,26.7Hg221.5Mg?+1,23.65.6.27Mn2*1.24.247.35Mnu33.86Ni2+(20r：)1,2,36.06,10.7743.09Pb2*26.32PdMOC)1.216.227.1Th123,48.8,16.242.56.7Ti3+1,2,310.43,18224.901,2,35.4,102,14.7Zn2+(30D12

15、4.98.8.81Zr*123,48.4,16.043.230.14草酸(Oxalic acid)HOOCCOOHAg+12.41Al*1,2,37.2643.0,163Ba2+1231Ca2+13.0Cd2*123.525.77Co2+1234.79,6.7.9.7Cl!”1,26.23,10.27f.2+L2,32.94525.22Fe?t1,2,3941620 2Hg2+19.66Hgi2+6.98123.43,4.38Mn2+1.23.975.80Mn1,2,39.98,1657,19.42、片1,2,35.3,7.64,8.5Pb2+124.91,6.76Sc5*123,46.86,

16、1131,14.32,16.70Th424.48Znu12,34 89,7.60,& 15Zr“1*49.80,17.14,20.8621.155乳跋 (Lactic acid) CHjCHOHCOOHBa2410.64C广11.42Cd：11.70Co2+11.90Cu2+1,23.02,4.8517.1Mg2+1137Mn2+11.43Ni212.22PbU2.40380Sc215.2Th*15.5Zn2+1,22203756水杨酸 (Salicylic acid) c6ii4oii)cooiiAl北114.11Cd15.55Co2*126.72,11.42Cr2*1,28.4.15.3C

17、u2-1.210.60J8.45F/+t2655 J 1.25Mn:+1,25.90,9.8。g1,26.95,11.75Th*123,44.25,7.60,10.05,11.60TiO2*16.09V-16.3Znu16.857模基水杨酸 l5-sulfosalicylic acid) HOCHxCOHlCOOHAlu(0.1mol/L)12,313.20.22.83,25.89Be24(01mol/L)1,211.71,20.81Cd4(0.1mol/L)1,216.68,29.08Co2(0.1mol/L)1.26.13.9.82Cr3(0.1niol/L)19.56CuO-lmol/L

18、)L29S2.16.45FSw.lmol/L)1.25.9.9.9F/o.lmoi/L)12314M2S.1832.12M0.lmol/L)1,25.24,8.24Ni2+(0.1moI/L)U642,10.24Zn(0.lmol/L)126.05,10.658酒石酸 (Tartaric acid) (HOOCCHOH)2Ba2+1.62Bi3+38.30Ca2+1.22.98.9.01Cd2*12.8Co2+I2.1Cu眼123,43.2,5.11,4.78,6.51Fe3+17.49Hg2*17.0Mg2+2 一1.36Ml?，1249Ni2*12.06PV133.78,4.7Sn2+15

19、2Zn2+1.22.68.8329丁二酸 Butanedioic acid) noocai2cn2cooiiBa2+12.08Be2+13.08Ca2+12.0Cd12.2CO，12.22Cu2+1333F己17.49H/27.28Mg2+11.20Mn2+12.26、产12.36P砂12.8Zn2+11.610(Thiourea)H1NC(=S)NH2Ag，1,27.4J3.1Bi3+611.9Cd2*123,40.6,L62.6,4.6Cu+3,413.0.15.4Hg2,2,3,422.14.7,26.8Pb2*123,41.4,347.8.311乙二胺 (Ethyoenediamine

20、)Ag+1.24.70,7.70Cd%20C)1,2,35.47,10.09,12.09H2NCH2CH2NH2Co2+123S.9L10.64,13.94Co1,2,318.734.9,48.69Cr2+1,25.15,9.19Cu*210.8Cu2+1,2,310.67,20.0,21.0Fe2+1,2,34.34,7.65,9.70Hg2+1.214.3,233Mg1037Mn:+1,2,32.73,4.79,5.67Ni“1,2,37.52,13.84,18.33Pd2+226.901,24.6,75Zn2+1,2,35.77.10.83,14.1112毗嚏(Pyridine)GH.N

21、Ag，121.97.435Cd2*12341.404.95,2.27,2.50Co2+121.144.54Cu2*12342.S9,4.33,5.93,6.54Fe2+10.711,2,35.1,10.0,10.4Mn:+1*41.92277,3.37,330Zn2+12,3.41.413.11,1.61,1.9313甘氨酸(Glycin)H2NCH2COOHAg1,23.41,6.89Ba2+10.77Ca2*1138CUS.iS7.S1.47iOJng113123HKM4N身由整J挪W4 ui陆3J.75jjl祯折彩1皿服扯ii.丘2I.1E3.tIA-J7545JJH.JXI?ik?IW

22、125-75.15H2w11).731临11械IS【树RJL971幡ii*34珈0-MCIHJWW胃utlJ91姑冲槌H占l-T?11，5i.i1杼U1514711.u3.7MK4J4H.?成1JJ.5JL3辿诚心IJ#L期1J3.4U1地38S.45MI.MH.9I.JH1J4JU1.54JUU-lJLRy.oIjmnJ.M2IE捋4.Lu珈1IJI.I?11/U21.7扫.襦Li皿心W91i-io111讪】.NI4.ZT4Jq心yjl-DI】1是.CK用44?JM7%而P.ltJJ1J.9JL2.0-iJ；5457JJ7-6JLH心wIM2.IIJ.I47JL47JXil财_7511：12.2IJI7.M7J?yj47ij4XW52.JI2.M144A*7J!*.RECflMA2.4ilJ.d-v俺由Wu.9jJ1J.9