《功能高分子材料课件1功能高分子概述》由会员分享，可在线阅读，更多相关《功能高分子材料课件1功能高分子概述（68页珍藏版）》请在装配图网上搜索。
1、表表11 各种高分子材料的产量和价格比各种高分子材料的产量和价格比*价格比以通用高分子为价格比以通用高分子为1计。计。前基板前基板汇流电极汇流电极透明电极透明电极 透明介质层透明介质层黑条黑条MgO保护层保护层后基板后基板数据电极数据电极障壁障壁荧光粉荧光粉封接浆料的涂布烧结封接浆料的涂布烧结前工序后工序排气充气封孔排气充气封孔检测检测CH2CHSO3HCH2CHCH2OCH2OONNOOO12C8H17Br +NaCN相转移催化剂280oCC8H17CN +NaBrCHCH2HCCH3COOHCONH2CHH2CCONH2CHCH3CONH2H3C3H+O-NH2COCOOH2OCCOOCH
2、3CH34CHCHCH2CHCHCH2OHOHCCOOCHCHCH2CCOO底物高分子催化剂ZXWY图1-1 高分子催化剂协同效应的示意图PVP +BrCH2COO-NNBr-+BrCH2COONNBr-+CH2COOBr-H2OH+CH3COOH+5CH2CHCHCH2CHCHCH2CHCCH3CH2OOCH2CHCH2OHOHCH3+HCHOH+OHCH3H2COHCH3H2COHCH3n-2H2CHCCOCl(C2H5)3NOCH3H2CCH3H2CCH3n-2COHCCH2OCOHCCH2OCOHCCH26AIBNOCH3H2CCH3H2CCH3n-2COHCOCOHCOCOHCCH2
3、CCH3CNH3CCH2H2CCCNCH3CH3OH-6 +H3CCCH3COOHHCCOOHH2CCCOOHH2CCCOOHH2CCCOOHCH3CH3Hn-2CHSO3HH2CHCSO3HH2C7+NCHH2CCHSO3-H2CHCSO3-H2C7NCHH2CH+NCHH2CH+-8聚合SO3-SO3-SO3-SO3-+N+N+N+NHHHH碱化，分离SO3NaSO3Na SO3NaSO3NaNNNN9NCHH2COHOC OHCCH2NHCH2COHOC OHC CH2NCH2H2COHOC OHCCH2聚合NCHH2COHOC OCH CH2NHCH2COHOC OCHH2CNCH2H
4、2COHOC OHCH2CNNNNNNHHH3COOHNHH10NNNNNRONRHHNHHHO11R:HC CH2H2CCCH3COOCH2CH2H2CHCCH2OH2CHCNH2COOH腺嘌呤A 胸嘧啶T 胞嘧啶C 鸟嘌呤G N NNNNNH2Na+H2CCCH3COOCH2CH2BrNNNNNH2CH2CH2OCCCH3CH2O12NNNNCH2CH2OOC CCH3CH2NHHNNOHCH2CH2OOCCCH2CH3CH3O13H2CHCNHCCHCCOOOHCHCCCOOONHC CH2 以马来酸酐为模版，4-乙烯基吡啶不需要引发剂即可聚合CHHCCHHCCHHCCNCNCNCNHC
5、CH2CNHCCH2CNHCCH2 射线CHHCCHHCCHHCCNCNCNCNCHCH2CNCHCH2CNCHCH2NHCH2CCu2NCHH2C+N+CH2H2C(H2C)4N+CH2H2CH2CCCOOCH3CH3H3CCH2COOCH3HCOHH2C(i-PrO)3AlH3CCOCH2CH3CHOAlH2COCCH3C2H5CH2CO+AlOCHCH3C2H5混合溶剂：丙酮：水=2：5水解速率常数：k=0.1 l/mol min.k=3.8 l/mol min.H2CCHCH2ClH2CCHCH2ClH2CHCCH2Cl1617H2CHCH2CHCCH2ClCH3OCH2ClZnCl2H2CHCH2CHCNH2Li1819H2CHCH2CHCCH2ClSO2Cl2,CH3OCH2OCH3无水ZnCl2,40OC,8小时P +X P-XRP+M+MkdkaxCat:HFInitiator:三甲基硅烯酮缩醛M:Polar MonomerCOMeOCH3Me2C=COSiMe3OMeMe2C=COSiMe3OMe+CatC=COSiMe3OMeMeCH2CMe2CO2MeMMA活性聚合物Reaction Condition:Room TemperatureCH2=C基团转移聚合基团转移聚合 GTP
功能高分子材料课件1功能高分子概述
