磷酸一铵MAP的MSDS

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1、MaterialSafetyDataSheetRevisionIssued:2/28/11Supercedes:02/28/2011FirstIssued:8/20/2007SectionI一ProductandCompanyIdentificationProductName:MAP(MonoammoniumPhosphate)ERGNo.:N/ACommonName:MonoammoniumPhosphateFormula:(NH4)H2PO4Synonym:MAPUses:AgriculturalSectionII一Composition/InformationOnIngredientsC

2、hemicalName：MonoammoniumPhosphateChemicalComposition:astotalP2O550%byWeightTotalNitrogen,asN10%byWeightFluorides,asF0.6%byWeightMoisture,as3.0%byWeightCASNo.7722-76-1*Forparticulatesnototherwiseregulated,standardis15mg/m3totaldustand5mg/m3forrespirablefraction.*Forparticulates(insoluble)nototherwise

3、specified,adoptedvalueis10mg/m3forinhalablefractionand3mg/m3forrespirablefraction.*Productcontainsmonoammoniumphosphateasessentialingredientwithsmallamountsofdiammoniumphosphate,ammoniumsulfate,urea,andaluminum/calcium/iron/magnesiumphosphatecompounds.SectionIII一HazardIdentificationPotentialAcuteHea

4、lthEffects:EyesandSkin:Contactmaycauseeyeirritationandprolongedcontactwithskinmaycausesomeirritation.Inhalation:Highdustconcentrationsofair-bornematerialmaycauseirritationofthenoseandupperrespiratorytractwithsymptomssuchassorethroatandcoughing.Inhalationofdecompositiongasescancauseirritationandcorro

5、siveeffectsontherespiratorysystem.Somelungeffectsmaybedelayed.Ingestion:Ingestionofsmallquantitiesareunlikelytocausetoxiceffect.Largequantitiesmaygiverisetogastro-intestinaldisorders.PotentialChronicHealthEffects:Noadverseeffectsareknown.CARCINOGENICITYLISTSIARCMonograph:NoNTP:NoOSHA:NoSectionIV一Fir

6、stAidMeasuresEyes:Immediatelyflusheyes(holdingeyelidsapart)withplentyofwaterforatleast15minutes.Getmedicalattentionifirritationdevelopsorpersists.Skin:Washskinthoroughlywithsoapandwater.Ingestion:Donotinducevomiting.Drinklargeamountsofwater(ormilkifavailable)todilutestomachcontents.Smallquantitiesar

7、eunlikelytocausetoxiceffect.GetmedicalattentionifalargeamountofMAPisingested(smallchildren,morethan50g).Inhalation:Removefromsourceofexposuretodusts.Obtainmedicalattentioniftheeffectsoccur.Personswhohaveinhaleddecompositiongases(e.g.inafire)shouldobtainimmediatemedicalattention.SectionV一FireFighting

8、MeasuresFlashPoint:Non-flammableAutoignitionTemperature:NotApplicableLowerExplosiveLimit:NotApplicableUpperExplosiveLimit:NotApplicableUnusualFireandExplosionHazards:MAPisanon-flammableinorganicsaltandisnotflammablehoweverwhenstronglyheated,MAPwilldecomposegivingoffammonia.ExtinguishingMedia:Chemica

9、ltypefoam,CO2(CarbonDioxide),drychemical,waterfog.SpecialFirefightingProceduresandEquipment:Keeppersonnelremovedfromandupwindoffire.Wearfullfire-fightingturn-outgear(fullBunkergear)andrespiratoryprotection(SCBA).SectionVI-AccidentalReleaseMeasuresSmallSpill:Spillageshouldbesweptupandplacedinchemical

10、wastecontainertobedisposedatanappropriatewastedisposalfacilityaccordingtocurrentapplicablelawsandregulationsandproductcharacteristicsattimeofdisposal.Adequateventilationisrequired.LargeSpill:Containspillandtransferthematerialtoappropriatecontainersforreclamationordisposal.Disposeofmaterialatanapprop

11、riatewastedisposalfacilityaccordingtocurrentapplicablelawsandregulationsandproductcharacteristicsattimeofdisposal.Adequateventilationisrequired.ReleaseNotes:Ifspillcouldpotentiallyenteranywaterway,includingintermittentdrycreeks,contactthelocalauthorities.IfintheU.S.,contacttheUSCOASTGUARDNATIONALRES

12、PONSECENTERtollfreenumber800-424-8802.Incaseofaccidentorroadspillnotify:CHEMTRECINUSAat800-424-9300;CANUTECinCanadaat613-996-6666CHEMTRECinothercountriesat(Internationalcode)+1-703-527-3887.Comments:SeeSectionXIIIfordisposalinformationandSectionXVforregulatoryrequirements.Largeandsmallspillsmayhavea

13、broaddefinitiondependingontheusershandlingsystem.Therefore,thespillcategorymustbedefinedatthepointofreleasebytechnicallyqualifiedpersonnel.SectionVII-HandlingandStorageVentilation:Usewithadequateventilation.Handling:UseappropriatepersonalprotectiveequipmentasspecifiedinSectionVIII.Avoidexcessivegene

14、rationofdustandavoidunnecessaryexposuretotheatmospheretopreventmoisturepick-up.Storage:Storeindry,wellventilatedarea,awayfrompotentialsourcesofheatandfire.SectionVIII-ExposureControls/PersonalProtectionEngineeringControls:Avoidhighdustconcentrationandprovideventilationwherenecessary.PersonalProtecti

15、on:EyeProtection:Weartightfittinggogglesindustyareastoreducedustexposuretotheeyes.ProtectiveClothing:Wearsuitablegloveswhenhandlingthisproductoverlongperiods.Ifskinirritationoccurs,wearlongsleeves.RespiratoryProtection:WearNIOSHapprovedrespiratoryprotectiveequipmentwhenexposureexceedstheOSHAnuisance

16、duststandardof15mg/m3ortheACGIHnuisancedustlimitof10mg/m3fortheeighthourtimeweightedaverage.Whenstoredinclosedarea,aself-containedbreathingapparatusisrequiredtoprotectagainstammoniagas.OtherProtectiveClothingorEquipment:Facilitiesstoringorutilizingthismaterialshouldbeequippedwithaneyewashfacilityand

17、asafetyshower.SectionIX-PhysicalandChemicalPropertiesAppearance/Color/Odor:OdorlessgranularsolidwithcolorrangingfromgraytogreenBoilingPoint:DecomposesMeltingPoint/Range:190CBoilingPointRange:NotApplicableSolubilityinWater:328g/L20oCVaporPressure(mmHg):2,000mg/kgbwAcuteInhalationToxicity:Nodataavaila

18、bleAcuteToxicity:OtherRoutes:NodataavailableAcuteDermalToxicity:(Rat)OECDGuideline402:LD505,000mg/kgbw.RepeatedDoseToxicity:NodataavailableToxicitytoAnimals:Eye&SkinIrritation/Corrosion:MildIrritantLowtoverylowtoxicitybasedonthestandardFederalInsecticideFungicideandRodenticideAct(FIFRA)ratingsformam

19、mals.DevelopmentalToxicity/Teratogenicity:NodataavailableBacterialGeneticToxicityIn-Vitro:GeneMutation:NodataavailableNon-BacterialGeneticToxicityIn-Vitro:ChromosomalAberration:NodataavailableToxicitytoReproduction:NodataavailableSpecialRemarksonToxicitytoAnimals:Carcinogenicity:NodataavailableOther

20、EffectsonHumans:PhosphatecompoundssuchasMAPareGenerallyRecognizedAsSafe(GRAS)byFDAforuseasafoodadditiveforbothhumanfoodandruminantfeedaccordingtoprescribedconditions.SpecialRemarksonChronicEffectsonHumansNodataavailableSpecialRemarksonOtherEffectsonHumans:NodataavailableSectionXII-EcologicalInformat

21、ionEPAEcologicalToxicityrating:Slightlytoxictopracticallynon-toxictoaquaticorganismsbasedontheFederalInsecticideFungicideandRodenticideAct(FIFRA)acutetoxicityratings.AcuteToxicitytoFish:(Oncorhynchusmykiss)96-hr:LC50=85.9mg/LChronicToxicitytoFish:NodataavailableAcuteToxicitytoAquaticInvertebrates:No

22、dataavailableToxicitytoAquaticPlants:NodataavailableToxicitytoBacteria:NodataavailableToxicitytoSoilDwellingOrganisms:NodataavailableEcotoxicityToxicitytoTerrestrialPlants:NodataavailableStabilityinWater:StableStabilityinSoil:StableEnvironmentalFate:TransportandDistribution:Calculated,fugacitylevelI

23、II:3.98x10-12toair,45.3%towater,54.6%tosoil,0.0755%tosediment.Phosphates,whetherwaterorcitratesoluble,aretranslocatedinthesoilonlyoververyshortperiodsandarethenimmobilized.Toxicity:Inorganicphosphateshavethepotentialtoincreasethegrowthoffreshwateralgae,whoseeventualdeathwillreducetheavailableoxygenf

24、oraquaticlife.Biodegradation:ThePhosphoruscycleiswellunderstood.Phosphatesareconvertedtocalciumoriron/aluminumphosphatesorareincorporatedwiththeDegradationProducts:organicsoilmatter.Photodegradation:NodataavailableSectionXIII-DisposalConsiderationsProductDisposal:Disposeofwasteatanappropriatewastedi

25、sposalfacilityaccordingtoapplicablelawsandregulations.Collectinappropriatecontainers.Disposeofatanappropriatewastedisposalfacilityinaccordancewithcurrentapplicablelawsandregulationsandproductcharacteristicsattimeofdisposal.GeneralComments:NoneSectionXIV一TransportationInformationUSDOTTDG-CanadaProper

26、ShippingName:NotregulatedNotregulatedHazardClass:IdentificationNumber:PackingGroup(TechnicalName):Labeling/Placarding:AuthorizedPackaging:Notes:EuropeanTransportation:SectionXV-RegulatoryInformationThisproducthasbeenreviewedaccordingtotheEPAHazardCategoriespromulgatedunderSection311and312oftheSuperf

27、undAmendmentandreauthorizationActof1986(SARAtitleIII)andisconsidered,underapplicabledefinitions,tomeetthefollowingcategories:Fire:NoPressureGenerating:NoReactivity:NoAcute:YesChronic:No40CFRPart355-ExtremelyHazardousSubstances:None40CFRPart370-HazardousChemicalReporting:ApplicableUNITEDSTATES:SARAHa

28、zardCategory:AllintentionalingredientslistedontheTSCAinventory.SARATitleIIIInformation:ThisproductcontainsthefollowingsubstancessubjecttothereportingrequirementsofTitleIII(EPCRA)oftheSuperfundamendmentsandReauthorizationActof1986and40CFRPart372:SARA(1986)ReportingChemical:MonoammoniumPhosphate,asP2O

29、552PercentbyWeightCASNO.7722-76-1CERCLASARA(1986)Reporting:311312313YesYesNoCERCLA/Superfund,40CFRParts117,302:IfthisproductcontainscomponentssubjecttosubstancesdesignatedasCERCLAreportableQuantity(RQ)Substances,itwillbedesignatedintheabovetablewiththeRQvalueinpounds.IfthereisareleaseofRQSubstanceto

30、theenvironment,notificationtotheNationalresponseCenter,WashingtonD.C.(1-800-424-8802)isrequired.WHMISHazardSymbolandClassification:ThisproductisnotWHMIScontrolled.CANADA:IngredientDisclosureList:Thisproductdoesnotcontainingredient(s)onthislist.EnvironmentalProtection:Allintentionalingredientsarelist

31、edontheDSL(DomesticSubstanceList).EINECS#:(MonoammoniumPhosphate)231-764-5California:Prop65:Thisisnotachemicalknowntocausecancer,norisitlisted.SectionXVI-OtherInformationNFPAHazardRatings:Health:1Fire:0Reactivity:0SpecialHazards:0=Insignificant1=Slight2=Moderate3=High4=ExtremeCOMMENTS:Section(s)chan

32、gedsincelastrevision:I,XII,XVAlthoughtheinformationcontainedisofferedingoodfaith,SUCHINFORMATIONISEXPRESSLYGIVENWITHOUTANYWARRANTY(EXPRESSORIMPLIED)ORANYGUARANTEEOFITSACCURACYORSUFFICIENCYandistakenattheuserssolerisk.Userissolelyresponsiblefordeterminingthesuitabilityofuseineachparticularsituation.PCSSalesspecificallyDISCLAIMSANYLIABILITYWHATSOEVERFORTHEUSEOFSUCHINFORMATION,includingwithoutlimitationanyrecommendationwhichusermayconstrueandattempttoapplywhichmayinfringeorviolatevalidpatents,licenses,and/orcopyright.